MSDS for N-Nonane

Identification

Product Name: N-Nonane
Chemical Formula: C9H20
Other Names: Nonane, n-Nonane, Shellsol 140
CAS Number: 111-84-2
Recommended Use: Laboratory chemicals, solvents, manufacturing of other chemicals
Manufacturer Contact: Typically found on product packaging, includes phone number for emergency help and business address

Hazard Identification

GHS Classification: Flammable liquid (Category 3), Aspiration hazard (Category 1), Specific target organ toxicity (Category 3, single exposure – narcotic effects)
GHS Pictograms: Flame, Health hazard, Exclamation mark
Signal Word: Danger
Hazard Statements: Flammable liquid and vapor, may be fatal if swallowed and enters airways, may cause drowsiness or dizziness
Precautionary Statements: Keep away from heat, sparks, open flames, avoid breathing vapor, use explosion-proof equipment, wear personal protective equipment, use only outdoors or in a well-ventilated area

Composition / Information on Ingredients

Chemical Name: N-Nonane
CAS Number: 111-84-2
Concentration: ≥99%
Impurities: Minor hydrocarbon impurities depending on supplier batch

First Aid Measures

Inhalation: Move person to fresh air, provide artificial respiration if breathing stops, seek medical attention
Skin Contact: Wash thoroughly with soap and water, remove contaminated clothing, get medical attention if skin irritation occurs
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present, continue rinsing, get medical advice if irritation remains
Ingestion: Do not induce vomiting, rinse mouth, immediately call a poison center or doctor

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, foam, or carbon dioxide
Unsuitable Extinguishing Media: Water jets, as they may spread the fire
Fire Hazards: Vapors can travel to an ignition source, flash back possible, combustion produces carbon monoxide and carbon dioxide
Special Protective Equipment: Full protective clothing and self-contained breathing apparatus for firefighters
Advice for Firefighters: Stay upwind, use water spray to cool exposed containers

Accidental Release Measures

Spill Precautions: Isolate spill area, remove ignition sources, avoid breathing vapors, provide ventilation
Containment: Prevent further leakage if safe, contain with inert absorbent material (sand, earth)
Clean-Up: Collect with non-sparking tools, place in labeled, tightly sealed containers for disposal
Personal Protection: Wear gloves, goggles, and appropriate protective clothing

Handling and Storage

Precautions for Safe Handling: Use only in well-ventilated area, ground and bond containers, avoid inhaling mist or vapor, keep away from heat, sparks, and flames, avoid contact with skin and eyes
Safe Storage Conditions: Store in tightly closed containers in a cool, dry, well-ventilated area, separate from oxidizing agents
Incompatibilities: Strong oxidizers, halogens
Special Packaging: Use containers designed for flammable liquids, keep containers upright

Exposure Controls and Personal Protection

Occupational Exposure Limit: OSHA PEL: Not established, ACGIH TLV: Not established
Engineering Controls: Use local exhaust ventilation, maintain adequate general ventilation
Personal Protective Equipment (PPE): Chemical-resistant gloves, safety goggles, flame-retardant protective clothing, in high vapor environments use respiratory protection such as an organic vapor cartridge respirator
Hygiene Measures: Wash hands after handling, remove contaminated clothing, do not eat or drink during handling

Physical and Chemical Properties

Appearance: Colorless liquid
Odor: Mild, gasoline-like
Odor Threshold: No data available
pH: Not applicable (neutral hydrocarbon)
Melting Point/Freezing Point: -54°C (melting)
Boiling Point: 151°C
Flash Point: 31°C (closed cup)
Evaporation Rate: Moderate (compared to butyl acetate=1)
Flammability: Flammable liquid
Lower Explosion Limit: 0.8% (V)
Upper Explosion Limit: 3.4% (V)
Vapor Pressure: 3.3 mmHg at 25°C
Vapor Density: 4.5 (air = 1)
Relative Density: 0.718 g/cm³ at 20°C
Solubility: Insoluble in water, soluble in organic solvents
Partition Coefficient (Log Kow): 5.65
Autoignition Temperature: 230°C
Decomposition Temperature: Not specified
Viscosity: Not measured

Stability and Reactivity

Stability: Stable under normal storage and use conditions
Reactive Components: Avoid contact with strong oxidizing agents, halogens
Decomposition Products: Carbon monoxide, carbon dioxide formed upon combustion or thermal decomposition
Hazardous Polymerization: Does not occur
Conditions to Avoid: Heat, sparks, open flames, static electricity

Toxicological Information

Acute Toxicity (Oral, Rat): LD50 approximately 15 g/kg
Inhalation: High vapor concentrations cause drowsiness, dizziness, central nervous system depression, at extreme exposure potential fatality
Skin Contact: Possible mild irritation, prolonged or repeated exposure may cause dermatitis
Eye Contact: May cause irritation
Aspiration Risk: Dangerous if swallowed and enters airways
Chronic Effects: Not classified as a carcinogen, mutagen, or reproductive toxin by major agencies; prolonged or repeated exposure can aggravate existing skin or respiratory conditions
Sensitization: Not reported

Ecological Information

Aquatic Toxicity: Harmful to aquatic life with long-lasting effects, may bioaccumulate in aquatic organisms
Persistence and Degradation: Not readily biodegradable, high potential for persistence
Mobility in Soil: Very low water solubility, likely to partition to soil and sediments
Bioaccumulative Potential: High (Log Kow >5)
Other Adverse Effects: Spills can create a film on water that impairs oxygen exchange affecting plants and animals

Disposal Considerations

Waste Handling: Collect liquid residues in sealable containers, label as hazardous waste
Disposal Method: Send to facility licensed for flammable liquid disposal, incineration under controlled conditions recommended
Contaminated Packaging: Handle as hazardous, rinse and offer for recycling or dispose in line with local regulations
Environmental Precautions: Do not allow to enter drains or waterways, notify authorities in case of large spill

Transport Information

UN Number: UN1920
UN Proper Shipping Name: Nonane
Transport Hazard Class: 3 (Flammable liquids)
Packing Group: II
Label Required: Flammable liquid label
Marine Pollutant: Yes
Special Transport Precautions: Avoid transport with oxidizers, follow all regional and national guidelines

Regulatory Information

OSHA Status: Hazardous chemical under the OSHA Hazard Communication Standard
SARA Title III (Sections 302/304, 311/312, 313): Not listed under extremely hazardous substances, fire hazard, immediate health hazard
TSCA Status: Listed on Toxic Substances Control Act Inventory
REACH Status: Registered and pre-registered substance in EU
WHMIS (Canada): B2 (Flammable liquid), D2B (Toxic material causing other toxic effects)
Other Regulations: Subject to national and local chemical safety regulations in various jurisdictions